Friday, July 31, 2020
19 Best Admissions Essay Images
19 Best Admissions Essay Images But, usually, we plan vacations to escape from our daily lives. This means that a look into your trip is probably not the best picture of what itâs like to hang out with you on any given day, which is what the goal of your common app essay should be. So if youâre the kind of person that has a ten-step bedtime routine that keeps the wheel in motion, and also recently went bungee jumping, you should stick with the bedtime routine. Smart College Visit is the educated way to search for college, find campus visit dates, get directions for college trips, and book hotels near campus. If sending test scores, Rutgers has no preference about which examination a student submits. Student athletes may choose test optional admission, but will be subject to NCAA eligibility standards for enrollment. Students with a GED diploma/certificate are required to submit their official results. A transcript of any and all high school work attempted is required in addition to the GED results. If you already have a SRAR account, created for use with another participating college/university, log in with your SRAR email address and password to complete the linking process for Rutgers. And of course it needs to be no more than 500 words. Because thatâs the rule, and even if itâs a narrow and arbitrary rule, you need to prove you can color inside the lines. In my next post to this site, Iâll give you some advice about how to write concisely and make the most of those, or any other, 500 words. It is mandatory to procure user consent prior to running these cookies on your website. Necessary cookies are absolutely essential for the website to function properly. Manage to define the importance of design in modern conditions and explain how, in your point of view, it might contribute to the development in general. Besides, try to give a personal definition of design according to personal experience. It would be great if you mention some famous people who made an input to the development of the design. You should use only the number of words you need to express your answer. Applicants are asked to submit a supplemental essay in addition to the Common Application or Coalition Application Personal Essay. This supplemental essay will allow you to further express your interest in your academic area of choice. To send a message directly to your admission counselor, visit the map and select your state. Remember, our team is here to help you through the application process! Please donât hesitate to call our office with any questions or concerns at or . While we donât want to limit you from fully expressing your ideas and responding to our supplemental essay question, we recommend that you keep your response to around 250 words. The word allowance on the Common Application and Coalition Application forms is 300 words. This is to give you flexibility and to ensure your essay is not cut off. Community might refer to your cultural group, extended family, religious group, neighborhood or school, sports team or club, co-workers, etc. Describe the world you come from and how you, as a product of it, might add to the diversity of the UW. Students should obtain a copy of their high school transcript from their school counselor and use the transcript as a reference when completing the SRAR. Military, are Military Veterans, or Military Dependents who plan to apply for educational benefits under the GI Bill receive a waiver of the application fee. Official Fee WaiversStudents who participate in the National School Lunch Program receive a waiver of the application fee. Explain your thoughts on how the University of Evansville will help you achieve your personal and professional goals. SECOND REVIEW A supplementary service for our previous customers. If you submitted an essay to us and want to resubmit the same essay after you revise it, we evaluate the revised essay and provide more advice. Our evaluation explains mechanical errors, strengths and weaknesses in your essay, and ways to improve it. We cover all aspects of the essay--its structure, organization, logic, style, and tone, as well as specific elements such as paragraphs, sentences, words, and transitions. We recommend composing in advance, then copying and pasting into the application. Double-spacing, italics and other formatting will be lost, but this will not affect the evaluation of your application. You may use this space if you need to further explain or clarify answers you have given elsewhere in this application, or if you wish to share information that may assist the Office of Admissions. If appropriate, include the application question number to which your comment refer. Our families and communities often define us and our individual worlds. This category only includes cookies that ensures basic functionalities and security features of the website. These cookies do not store any personal information. The company has equipped itself with the most modern and recent software, programs and applications to sieve any form of plagiarism.
Sunday, May 24, 2020
The Women In ââ¬ÅTriflesââ¬Â. The Play ââ¬ÅTriflesââ¬Â , Written By
The Women In ââ¬Å"Triflesâ⬠The play ââ¬Å"Triflesâ⬠, written by Susan Glaspell allows us to experience the gender divide in the early nineteen hundreds. While the play title gives the reader the idea that the story will be trivial or unimportant, it is anything but. The play focuses on the fact that women are considered ââ¬Å"otherâ⬠or an ââ¬Å"objectâ⬠(Beauvoir, 8). This is the complete opposite of men who are considered the ââ¬Å"subjectâ⬠, which holds immense amount of values. These two definitions are polar opposites. In the piece Second Sex, Beauvoir goes onto explain that this distinct difference between genders cause women to lose their humanity or individuality. In this world, women have no authority since they are nothing more than objects for men toâ⬠¦show more contentâ⬠¦From the beginning of the play it is obvious that our characters are vastly different levels of importance. The men gain their importance from the type of people they are. The women, on the other ha nd are defined by the men that they have married. The critic Beauvoir mentions in chapter five of The Second Sex that ââ¬Å"Marriage is the reference by which the single woman is definedâ⬠(Beauvoir, 502). In society a woman only hold value based on the man that she has married. In ââ¬Å"Triflesâ⬠all the men are addressed by their birth given first or last names. However all the women within the play are addressed by their last name given to them by marrying their husbands. Beauvoir goes onto say that marriage was supposed to be a free choice between both spouses and that the desire of marriage should be reciprocal. However, it has developed into a woman s responsibility to marry, take her husband s last name, stay at home and be a housewife (Beauvoir, 502). This concept is portrayed when Mrs. Hale describes Minnie before she married Mr. Wright: ââ¬Å"I heard she used to wear pretty clothes and be lively, when she was Minnie Fosterâ⬠(Glaspell, 984). Minnie was once her own individual who lived her life depending on what she wanted to do. However, once she married Mr. Wright she lost her individuality and became his object. When she was with her husbandShow MoreRelatedCharacter Analysis Of Susan Glaspell s Trifles 1714 Words à |à 7 PagesPaper 2 In both A Rose for Emily written by William Faulkner and Trifles written by Susan Glaspell loneliness, poverty and isolation consume the lives of the characters. Susan Glaspellââ¬â¢s play ââ¬Å"Triflesâ⬠written in 1916. In this play the authorââ¬â¢s talks of her preoccupation with culture- bound notions of gender and sex roles. Glaspell says women are considered trifles which mean they are not important to society which is carried out by men (Baym, p. 742). In Trifles written by Susan Glaspell the time isRead MoreTrifles : Susan Glaspell s Trifles940 Words à |à 4 PagesWhat is a trifle? A trifle is something that has little to no importance (dictionary.com). For instance, the color of your nails would be considered a trifle. In Trifles by Susan Glaspell, women are criticized and made fun of by men because of the little things they worry about, such as the color of their nails or their hair. This exhibits the gender role difference portrayed during the playââ¬â¢s t ime period. The central conflict is what the plot is centered around. In Trifles, the central conflictRead MoreCritical Analysis Of Trifles By Susan Glaspell1016 Words à |à 5 PagesPerspective: Readers Response Criticism to ââ¬Å"Triflesâ⬠by Susan Glaspell The play written by Susan Glaspell in 1916 is based on the murder of John Wright where the prime suspect is his spouse; Minnie Foster. ââ¬Å"Triflesâ⬠is fixated on the investigation of the social division realized by the strict gender roles that enable the two men and women to have contending points of view on practically every issue. This is found in the way the men view the kitchen as they consider it as not having anything of significantRead MoreSusan Glaspell s A Jury Of Her Peers995 Words à |à 4 Pages The subordination of women was a prominent theme in the 1900ââ¬â¢s, during a time when women were often treated as second class citizens to men. Susan Glaspell wrote the play ââ¬Å"Trifles,â⬠in 1916, which portrayed how womenââ¬â¢s lives were seen as less significant throughout American society. The following year, Glaspell wrote the short story ââ¬Å"A Jury of Her Peers,â⬠which was essentially a longer and more detailed version of ââ¬Å"Trifles.â⬠The stories are alike in many societal implications, since ââ¬Å"A Jury of HerRead MoreTrifles : A Dramatic Examination Of Gender Role1031 Words à |à 5 PagesTrifles: A Dramatic Examination of Gender Role Trifles is a dramatic one act play written by American female playwright Susan Glaspell. The play examines through the framework of a murder mystery how rigid gender role dynamics in the early 20th century not only shaped people s thinking, but blinded them from seeing what would otherwise be clear as day to someone else. During the time the play was written the women s liberation movement had yet to take place. Women were strongly stereotyped andRead MoreSusan Glaspells Trifles1479 Words à |à 6 PagesSusan Glaspellââ¬â¢s 1916 play titled ââ¬Å"Triflesâ⬠uses many elements of drama such as, diction and spectacle through the actions of the two women as they rummage through a unusually messy kitchen to develop complexity and hold the attention of the audience until the very end. Glaspell uses irony and common misconceptions to convey her powerful message ââ¬Å"Triflesâ⬠is also a play that reflects a clear notion of gender and sex roles. Glaspell, a feminist writer, writes plays that are known for their developmentRead MoreSusan Glaspell s A Jury Of Her Peers Essay1164 Words à |à 5 Pagesmurder trial where Margaret was eventually convicted of murdering her husband, John Hossack. Shortly after covering the trial, Glaspell quit journalism and started writing novels, short stories and plays. Two of which were based on her coverage of the Hossack Case. One was a one-act play titled ââ¬Å"Triflesâ⬠and the other was a short story entitled ââ¬Å"A Jury of Her Peersâ⬠. During the coverage of the Hossack Case in the newspaper articles, Glaspell writes of the murder trial as it unfolded. The charactersRead More Gender Roles in Susan Glaspells A Jury Of Her Peers and Trifles 1176 Words à |à 5 PagesPeers and Triflesà à Twentieth century society places few stereotypical roles on men and women.à The men are not the sole breadwinners, as they once were, and the women are no longer the sole homemakers.à The roles are often reversed, or, in the case of both parents working, the old roles are totally inconsequential.à Many works of literature deal with gendered roles and their effect on society as a whole or on an individual as a person.à A Jury Of Her Peers and Trifles, both written by SusanRead MoreFeminist in Susan Glaspellà ´s Play Trifles999 Words à |à 4 Pages Trifles In Susan Glaspellââ¬â¢s play Trifles a man has been murdered by his wife, but the men of the town who are in charge of investigating the crime are unable solve the murder mystery through logic and standard criminal procedures. Instead, two women (Mrs. Hale and Mrs. Peters) who visit the home are able to read a series of clues that the men cannot see because all of the clues are embedded in domestic items that are specific to women. The play at first it seems to be about mystery, but itRead MoreSusan Glaspell s Trifles 904 Words à |à 4 Pages Trifles is a play written in 1916 by author Susan Glaspell. It is considered to be one of the earliest pieces of American feminist literature. Feminism is a political movement which seeks to establish equal social and political opportunities for women. In Trifles, the women are looked upon as unimportant and inferior to the men in being able to help solve the case. The story opens with the sheriff, county attorney and their wives coming to pick up some clothes for Minnie who has been arrested
Wednesday, May 13, 2020
Leader Who Liberated The Indian Sub-Continent - Free Essay Example
Sample details Pages: 1 Words: 391 Downloads: 1 Date added: 2019/08/06 Category People Essay Level High school Topics: Mahatma Gandhi Essay Did you like this example? History bears witness to the rise and fall of kingdoms, dynasties and revolutions over the years and there is one key element that is found to be common in every era. That is the presence of a leader who united the people under one cause. The type and quality of leadership is pivotal to the survival and success of a group. Effective leadership with proper structure and organization can lead the masses to victory and fulfilment. In this paper, I chose to talk about a leader who liberated the Indian sub-continent from the colonial rule spanning nearly two centuries. à A land known for its rich culture, heritage and diversity, India was called the golden bird because of its abundant raw materials, precious stones, gold and other riches. Foreigners saw it as the perfect quest for wealth and prosperity. Invaders from all over the world have been documented to embark on a journey to India, either to loot and plunder or to establish some sort of permanence on the Indian soil. The Arabs, the Mongols, the Persians, in addition to their European counterparts from France, Portugal, Denmark and the Netherlands, all invaded India at some point. However, the one that lasted till modern times was the British Raj which started as the East India Company, initially a trade establishment that later went on to exert control, dominance and ultimately, colonization. Donââ¬â¢t waste time! Our writers will create an original "Leader Who Liberated The Indian Sub-Continent" essay for you Create order The general population of India suffered large scale exploitation at the hands of the imperial rule. Apart from discrimination in the political and economic scenario, Indians were treated as second-class citizens in their own motherland. A once rich and affluent country was slowly losing its wealth and grandeur to the foreign entity. This brought about feelings of deep resentment and created the need for sovereignty. They say when human hardships are at its peak, a messiah emerges to empower people and lead them to victory. In my opinion, India needed her fair share of extraordinary men and women who could bring back her lost freedom and among those brave people was a man so rare and remarkable that an entire sub-continent still reveres him as the father of the nation. As an Indian, I understand that we paid a tremendous price for freedom and Mahatma Gandhi will always be at the apex of our identity as proud nationals of a free country.
Wednesday, May 6, 2020
The Do My Term Paper for Me Stories
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Tuesday, May 5, 2020
Anchoring script free essay sample
Indian Parliament adopted the Indian Constitution, elevating India to the status of a sovereign republic. This is not just a celebration like any other celebration. This is the celebration of the vision and sacrifices made by our founding fathers. Today we have all gathered here to celebrate this special day. I request to please come on the stage and chant ved mantra to make this more auspicious. Thank you Sir I now request to deliver the welcome address Thank you very much sir, your thought provoking address set a perfect platform for the start Om namovasudevaay namah Krishna, Krishna kaa naam lete hi poora vatavaran prem may ho jaata hai, par unke viyog se hum jaise jal bin machli ho jaate hain Isi virah ko odissi nritya ke maadhyam se darshaane aa rahi hain Incredible and excellent performance by our nanhe munne Yeh saari cheezein toh hum aapko bata diye ab dekhte hain aap kitna jaante hain To ho jaaye Dimaagi Kasrat. We will write a custom essay sample on Anchoring script or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page Kuch naye sawaalon ke saath aa rahe hain Please give a big round of applause to him and I wish you all the best. Fabulous performance. I hope you agree too. Bhara nahin jo bhaavon se, behti jismein ras dhaar nahin Wah hriday nahin patthar hai, jismein swades ka pyaar nahin Agar in panktiyon ne aaj hamein itni prerna di hai toh sochiye uss zamaane ke kavi toh kamala hi kar dete the. Unki kavitaayein hi logon ka prerana stotra bani Aisi hoti hai Kavya ki shakti jo hamaare antar atma ko jhakjhor deti hai. Today we also have a few poets among us, so recreating the ambiance of a kavi sammelan, I invite The sanchalak of the kavi sammelan, to introduce us with all the poets and enlighten us with their thoughts. A big hand for all the poets. It was actually an exceptional, outstanding and marvelous act. In sab kavitaaon ne hamein deshbhakti ke rang mein rang diya hai. Isi rang mein ranga hua ek geet prastut karne aa rahe hain Please welcome him with a big round of applause. With this we come the end of our cultural program. May I please request to please share his valuable thoughts with us, sir please. It is also time for us to do away from the blaming the society and the government. John F Kennedy said. ââ¬Å"Ask not what your country can do for you; ask what you can for the countryâ⬠. On this auspicious day we declare that we practice what we have preached and we hope you all do the same. Thank you very much Anchoring script free essay sample I heartily welcome our Honorable chief guest our Principal, Dear Teacher and all my friends. I further welcome the parents, relatives and lovely students. As you know today we all have gathered here for the annual day celebration. Sanjay Sir: We will have our traditional auspicious LAMP- LIGHTENING ceremony as a tribute to Mother Saraswati Goddess of Knowledge. That the by our chief guest Mr. ____________ Sir Please, LAMP-LIGHTENING( By all the guest)- Sanjay Sir: Now we consider that according to our Indian Tradition any auspicious work should be started with prayer Mamta: So I would like to call the prayer team from std. _______HM. PRAYER- Guest welcome with rose Tilak (Shailesh bhai- Manjeebhai-Kalluram) Sandeep Sir (Welcome speech) Hansika: Next, I would like to call upon our respected Principal Mr. Jaswin Sir to present a brief agenda and give the school presentation. Sir Please, -PRINCIPAL SPEECH- Hansika: My friend do you know According to religious tradition who is the first worshipable? Shalu: I guess you must be talking about Lord Ganesha. We will write a custom essay sample on Anchoring script or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page Hanshika: Yes, You are absolutely right, now we will have our traditional dance based on Lord Ganesha So, I request our students please come on the stage. Mamta: Participantsââ¬â¢ are____________ Ganesha Shalu: Dear, you have only senior students, why not Junior? Hansika: Itââ¬â¢s not like that, we have not only senior students but also junior. Annual Function is celebrated by many organisations (school/college/institute/university etc. ) for completing a successful year. In this article complete information on anchoring script for Annual Function is provided. Welcome ceremony: To start the welcome ceremony first wish to all the present audience according to time i. e. Good morning/ good afternoon/ good evening to all of you; On the behalf of the . Organisation. Name.. I First Anchor Name I Second Anchor Name (If two anchors are present) welcome our chief guest, guest of honour, principal other guests (guest will be decided by the management), students and participants. Today is a very great day that our ââ¬Å"Origination Nameâ⬠celebrating his ââ¬Å"time periodâ⬠Annual day. Friends we are living in that country on which we remember our ââ¬Å"Godâ⬠before starting any good work. Now I invite our chief guest, guest of honour all the other dignitaries present on the stage for lighting the lamp in front of ââ¬Å"MA SARASWATIâ⬠. Now the entire guest will move for lighting the lamp] We are also inviting girls for singing ââ¬Å"Saraswati Vandanaâ⬠. Now girls will start singing the saraswati songs. After finishing this event say thank you sir madam OR thankââ¬â¢s to all of you Now itââ¬â¢s time to welcome your all guests which you can call one by one person from your organisation they will welcome your all guests by giving flowers or any things which the management provide. Guest Speech: In this section you can call to your every guest one by one they will express their views about motivating the students. After every guest speech you will say thank you sir/madam also say 2-3 lines which he/she told in there speech. Cultural Events: Now that moment has come for which the students are waiting . â⬠yes.. â⬠the cultural event time. Now both anchors will start there anchoring by speaking one line/paragraph each other. Welcoming (Lightning of Lamp) Good evening. Itââ¬â¢s an honor itself to honour this beautiful audience who has gathered here. I Simran/ Anushka with my co-host Anushka/ Simran welcome you all on behalf of whole global family on this â⬠¦Ã¢â¬ ¦.. Annual Function. Thank you all for giving us your prized time. Before the launch, let me first acknowledge the presence of some of our eminent guests, â⬠¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦.. we will have our traditional auspicious LAMP-LIGHTENING ceremony as a tribute to Mother Saraswati, the Godess of knowledge. (Mother, we pray for your blessings with all humility ââ¬â give us wisdom to make this world abetter place. May all human beings live in harmony with nature and other forms of life. May the truth prevail. May the darkness of ignorance be swept away by the dawn of self-realization.)that the by our honourable Chief Guest His Highness Mr â⬠¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦.. Saraswati, the goddess of knowledge and arts, represents the free flowof wisdo m and consciousness. She has four hands representing four aspects of human personality in learning: mind, intellect, alertness and ego. With her other two hands she plays the music of love and life on a string instrument called the veena. She is dressed in white ââ¬â the symbol of purity ââ¬â and rides on a white swan ââ¬â symbolizing Sattwa Guna or purity and discrimination. vkse ljLorh egkHkkx,s fon~;s deyk ykspusA
Friday, April 3, 2020
Palladium Catalysis the Suzuki Reaction free essay sample
This step cannot occur in the absence of base and the exact mechanism have not been stated. 2 Boron ââ¬Å"ateâ⬠complexes ,via forming a quaternization of the boron with a negatively charged base, are mostly frequent seen explanation. 3 An isomerization from trans complex to cis complex is required before the reductive elimination can undergo. The reductive elimination is the final step which gives the desired product and also reproduces the palladium catalyst. The regenerated palladium catalyst would participate in the reaction again to synthesize more products. In experiment, a ligandless palladium catalyst, Pd/C was used which is easier to handle and can be remove by simple filtration. The generalized catalytic cycle shown above is specific to palladium catalyst with ligand, such as triphenylphosphine. The procedure in this experiment could be applied to cross-coupling Suzuki reation of a variety of iodophenols and arylboronic acids, giving the corresponding hydroxybiphenyls . In many cases, the coupling products are obtained quantitatively. We will write a custom essay sample on Palladium Catalysis: the Suzuki Reaction or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page 3 Experiment Modifications were applied in the experiments. The filter paper was washed by 5mL of methanol and transferred the solution into 25mL Erlenmeyer flask since there was a little amount of crude product collected by suction filtration. 5mL of water was added to the solution instead of 10mL. There was no solid left in the flask before heating the solution on steam bath. The flask containing reaction solution was heated on the hot plate to evaporate the excess of methanol after it was cooling in the ice-bath. Due to limit of time, the flask was placed into the fume hood for one week after a few minutes of heating. The final product was obtained after one-week-long methanol evaporating process. Filtered the reaction mixture by suction, a white/greyish solid was collected in the filter paper. Recrystallized this solid, white solids were obtained with a close melting point to that of final product. The NMR spectrum of this solid also showed the aromatic peaks. This solid was suggested as an intermediate of reaction, mostly likely ArOH-Pd-Ar in reductive elimination. Since a ligandless palladium catalyst was used in this reaction, a transformation from trans complex to required cis complecx was unnecessary. The unreacted intermediate may be left on the filter paper. This complex contained two phenyl groups which gave the aromatic peak in NMR spectrum. Because of the presence of the palladium catalyst, this complex cannot be soluble in the reaction solution and precipitate on the filter paper. Due to similar structure and functional groups presented, its measured melting point was close to that of the final product. When added 2M HCl into the filtrate until the entire solution was acidic, white cotton-like product was generated at the bottom of the beaker. A few minutes later, this product turned to be slight tan color. Since the reaction was performed in a basic aqueous media, the reaction was quenched by acidification with diluted HCl to precipitate the coupling product. Filtration would give the crude yield of product. At the beginning of the filtration, white product was collected on the filter paper; however the solid became less and less when adding more acidified filtrate, and washed the product with 10mL of water, only small amount of product was left on the filter paper. This unexpected situation stated that most of the products synthesized were actually soluble in water which was disagreed that the biphenyl-4-ol is insoluble in water. It was also the first indication of undesired product synthesized. Modifications were applied to recrystallization. 5mL methanol was used to wash off the products left on the filter paper. There was no solid precipitated when added 5mL of water into the flask containing reaction solution. When cooled the reaction solution in ice bath after heating on steam bath, there was no product was crystallized. The cooled solution reheated on the steam bath to evaporate excess of methanol. This evaporating process lasted for one week in the fume hood due to limit of time. Backed to the lab, wet product was obtained in the bottom and wall of the flask. The appearance of the product was slight red and mixed with some small spots of white solids. Due to the wetness of product, the melting point was unable to be measured directly. 2mL of methanol was added to the flask which was prepared for further recrystallization process. Since all the products dissolved in the methanol, the reaction solution was heated on the hot plate to evaporate the methanol. The product was regenerated, however, the red color turned to be darker and the white spot tended to show tan color. The appearance of experimental product was totally different from expected light tan color, which was second indicator of undesired product synthesized instead of biphenyl-4-ol. The measured melting point of this product was higher than literature value, which indicated the presence of impurities. Also, it was the third evidence of undesired product synthesized. The yield of product was only 11. 94% that was significant lower than high efficient yield from literature. This low yield was resulted from many aspects. The reaction condition in literature is halophenol (1mmol), phenylboronic aicd (1mmol), potassium carbonate (3mmol), Pd/C (3mg, 0. 3mol%) in 10mL of water at 50? for 12 hours, giving great than 99% yield. 3 Sakural et al3, they also demonstrates that when 0. 3mol% of Pd/C supended in aqueous potassium carbonate solution, was treated with stoichiometric amounts of 3-iodophenol and phenyboronic acid, the yield of 3-hydroxybiphenyl were 30%, 64%, 88%, 97% and 97% with quenching after 3, 6, 9, 12 and 24 hours. From their works, the reaction time plays an important role in yielding. Since limit of time during our experiment, the acidification was directly followed the second suction filtration. Insufficient reaction time gave the relatively low yield of our product. Since the yield of product was significant low, the amount of methanol added according to the lab manual was always excess, which became a barrier for the products to be precipitated from reaction solution. Thus, the evaporation process of methanol lasted for one-week-long. To improve this experiment, a longer reaction should be considered. As mentioned before, the experimental produce may not be the desired biphenyl-4-ol. It can be proved by the appearance of the product and deviation of measure melting point. Since there were no reagents or intermediate showing red color, the identification of the final product required further detection, such as chromatography, mass relationship and NMR spectrometry. Possible deviation may arise from improper operation and side product in the reaction. The possible side products would not be discussed here since it was beyond current level of knowledge. The Suzuki reaction is important in organic chemistry since it can achieve a numerous of organic transformation. It has some general advantages: can be conducted under mild reaction condition; can use common organoboronic acids; inorganic by-products are easily removed from reaction mixture,;it is stereoslective reaction; it is less toxic than other competitive method (since boronic acid are environmentally safer and less toxic than organostannanes, in our case, the palladium-charcoal is a ligandless catalyst which is convenient and environmentally friendly); the reaction can take place in the presence of other functional groups (which means protecting group is not always necessary). Even the Sukuzi cross coupling is versatile, there are still some shortcomings: aryl chlorides react slowly; sp3-hybridized alkyl halides sometimes show no reactivity; in the absence of the base, multiple side reactions are possible. 3 Other kind of palladium-catalyzed cross coupling reactions, such as the Stille cross-coupling, Kumada coupling, Sonogashira coupling and the Heck reaction are also important in organic transformation. Here are some vital synthetic applications: synthesis of Myxalamide A which is observed to have antibiotic and antifungal activity; synthesis of Oximidine II which is highly biologically active and affect the cell cycle at G1 Phase; and synthesis of KDR Kinase Inhibitor which inhibits the activity of specific tyrosine kinase enzyme in the body. 2 Conclusion During this experiment, a palladium-charcoal catalyzed Suzuki cross coupling was performed using phenylboronic acid, p-iodophenol and potassium carbonate in water.
Sunday, March 8, 2020
Multi-draft narrative of Mr Nobody Essay Example
Multi Multi-draft narrative of Mr Nobody Paper Multi-draft narrative of Mr Nobody Paper Directed and written by Jack Van Dermal, Mr.. Nobody is a brilliant film that portrays the timeless theme of lifes choices and possibilities in a refreshing and dazzling manner. Despite the complex and unconventional narrative structure of the plot, Dermal demonstrates his extraordinary skills of storytelling through presenting to the audience a magnificent film with a form more complicated than Tom Testers Run Lola Run and a theme broader than Peter Hotpots primary focus on love in Sliding Doors. This essay will analyze how the the seven key conventions defined by Borrowed (2002) are defied by or applied on the films multi-draft narrative. The film begins with a montage showing four deaths of Memo at the age of 34him lying in morgue, him drowning in his car under water, him being shot in the bathtub, and him waking in an explosion of a space shuttle. The quick scenes are then closely followed by 118-year-old Memo waking up in 2092, looking as if he is confused over his own past. His memory appears to have paused in 2009 as he claims to be 34 years old. With the help of his doctor, Memo begins to recount his whole life right room the start. These parts of Memos story, his childhood and old age, are in a somewhat linear narration. The voice-over of young Memo explains that the unborn children know everything about the past and future until the Angels of Oblivion place a finger on their lips and make them forget. Being missed by the angels, Memo chooses his own parents and comes to the world knowing everything. He knows, from the very beginning, that certain things are meant to be. He also ponders upon existence and the irreversibility of time, which are brought up in the later parts of the elm over and over. At the age of 9, Memo realizes the difficulty of choosing and faces the first crossroad of his life, from which point the film complicates into a multi-draft narrative. We cannot go back. Thats why its hard to choose. You have to make the right choice. As long as you dont choose, everything remains possible. With that in mind, little Memo chooses not to make a choice between two kinds of dessert or among three of his future partners. The audiences see Memo marrying all three of them at the similar age but in different lives. All parallel narrative begins when Memo faces the most critical decision of his lifedeciding which parent he should live with after their separation. This can be seen as the first branching point of Memos lives. Memo marries three women, Anna, Elise and Jean, has different Jobs and dies in different incidents all in similar age, indicating that the film conforms to Bordellos fifth convention: forking paths often run parallel. In the first narrative, Memo follows his mother and falls in love with Anna. Choosing to stay with his father in the second ND third narratives, Memo falls for Elise and Jean respectively. In one of these two narratives Memo writes his own novel about traveling towards Mars on a shuttle, which makes the fourth narrative. Each of these forking paths is linear on its own, keeping to Bordellos first convention: each path, after it diverges, adheres to a strict In these parallel narratives, Memo keeps changing the courses whenever he encounters unpleasant incidences, such as the several deaths mentioned above. For example, in the second narrative, Memo falls in love with Elise who does not return is affection. Heartbroken, he gets into a horrible bike accident and becomes paralyzed. Yet as soon as the viceroy says Vive got to get out of here. Go back. Before the accident, the audiences watch the accident rewind and Memo making a slightly different decision then eventually marrying the girl of his dreams. The protagonist defies death and reverses time. Here, the film adheres to the sixth convention: the forking paths presuppose the previous ones, as Memo makes the wiser choice in the second narrative. On the whole, Memo wants to reinvent his own life while the doctor and the interviewer aim to make sense of Memos stories and find out which of them is true. In this sense, it can be said that the characters of Mr. Nobody are somewhat goal- oriented. Everything you say is contradictory. You cant have been in one place and another at the same time. Of all those lives, which one is the right one? asks the interviewer. This line shows that the film is self-reflective as it is clearly aware of the nature of its unconventional narrative. The forking paths of Memo consist of recurrent characters and background conditions across the different lines of action (Waded, 2009) which is Bordellos third convention. For instance, whichever path Memo takes, he always runs into Anna, the woman who loves him as much as he does her. Not only does it show the intersection of the multiplicity, it also highlights the love theme of the filmone cannot possibly be happy with someone if the affection is not mutual. That is why Memo is not happy with either Elise or Jean. As Memo changes the course of his lives repeatedly, the audiences could not help but ender which fragment is his real life and whether the things he says are true at all, especially when all his alternative lives literally collide together towards the end of Memos recollection. In the narrative where he stays with his dad, marries but loses Elise to an accident, Memo escapes the death of drowning that he would have had in another narrative, but is told by his neighbor that he is drowned. The Memo in yet another narrative who is typing in a house then finds himself in danger of drowning as the house is suddenly flooded with water. Multiple circular narratives merge into nee. Towards the end, the seemingly linear narrative of the entire film is broken down as 118-year-old Memo tells the interviewer that neither of them really exists, because they are only imagined by a nine year old child faced with an impossible choice. Memo eventually dies at the time he has predicted he would, but as soon as he does, time rewinds quickly all the way to his childhood, echoing with Memos earlier statement to his younger self, For me, time is inverted. I start at the end of the story and go toward the beginning and confirming that he has truly always known everything about the past as well as the future. The film ends, leaving its audiences In conclusion, Mr. Nobody complies with four out of seven key conventions of Bordellos, showing that it goes beyond traditional narrative norms. The narrative might be more closed than open in each single forking path, but it is definitely open in terms of the whole film. The mysteries of Memos life have not been solved, leaving the audiences with plenty information gaps and room for interpretation. Nonetheless, the director has made his point rather explicitly through Memos answer o the interviewers confusion, Each of these lives is the right one!
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